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This 2-D nanosheet expands like a Grow Monster

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Posted April 21, 2018

Grow Monsters. Expandable water toys. Whatever you call them, they’re plastic-like figurines that swell when placed in water.

The simulation (single frame) shows molecules struck by light causing the 2-D nanosheet to expand. Credit: Richard Remsing, PhD, Temple University.

New materials science research borrows from this concept; only instead of water, engineers discovered that tiny crystal lattices called “self-assembling molecular nanosheets” expand when exposed to light.

The advancement, described in the Proceedings of the National Academy of Sciences in March, could form the backbone of new light-powered actuators, oscillators and other microscopic electronic components useful in the development of artificial muscles and other soft robotic systems.

The work centers on a materials science concept known as photostriction, which means turning light directly into mechanical motion, says the study’s co-lead author Shenqiang Ren, a researcher at the University at Buffalo’s RENEW Institute, which works to solve complex environmental problems.

“In this case, we’re using light — anything from sunlight to a simple laser — to cause the two-dimensional nanosheet to expand at an incredibly fast rate,” he says.

How fast? Sub-milliseconds. The process is aided by the photostrictive effect, which essentially bypasses the need to create electricity to move something, says Ren, PhD, a professor in the Department of Mechanical and Aerospace Engineering in the UB School of Engineering and Applied Sciences.

The nanosheet — made of the molecular charge-transfer compound DBTTF and buckyball molecules) — can expand up to 5.7 percent of its original size, according to the study.

While that may not sound like much, consider this: a 200-pound man that expands 5.7 percent would need to add 11.4 pounds in less than a second to keep pace with the light-triggered nanosheet.

Expandable water toys grow much more than that, but they do not revert to their original size. By contrast, the nanosheet does, making it potentially very useful as a light-induced actuator in artificial muscles, which has applications in everything from medical devices to industrial robotics.

Source: State University of New York at Buffalo

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