Google Play icon

Graphene oxide ‘paper’ changes with strain

Share
Posted January 20, 2016

The same slip-and-stick mechanism that leads to earthquakes is at work on the molecular level in nanoscale materials, where it determines the shear plasticity of the materials, according to scientists at Rice University and the State University of Campinas, Brazil.

Graphene oxide layers deform evenly under gentle strain, according to experiments and computer models by Rice University researchers. They discovered that the mechanical properties of the material change, depending on the rate of strain. Image credit: Ajayan Research Group/Rice University

Graphene oxide layers deform evenly under gentle strain, according to experiments and computer models by Rice University researchers. They discovered that the mechanical properties of the material change, depending on the rate of strain. Image credit: Ajayan Research Group/Rice University

The Rice lab of materials scientist Pulickel Ajayan found that random molecules scattered within layers of otherwise pristine graphene affect how the layers interact with each other under strain.

Plasticity is the ability of a material to permanently deform when strained. The Rice researchers, thinking about future things like flexible electronics, decided to see how graphene oxide “paper” would handle shear strain, in which the sheets are pulled by the ends.

Such deep knowledge is important when making novel advanced materials, said Chandra Sekhar Tiwary, a lead author of the new paper in the American Chemical Society journal Nano Letters and a Rice postdoctoral research associate.

“We want to build three-dimensional structures from two-dimensional materials, so this kind of study is useful,” he said. “These structures could be a thermal substrate for electronic devices, they could be filters, they could be sensors or they could be biomedical devices. But if we’re going to use a material, we need to understand how it behaves.”

This graphene oxide “paper” was analyzed for its mechanical characteristics under strain by Rice University researchers. They discovered that the mechanical properties of the material change, depending on the rate of strain. Image credit: Ajayan Research Group/Rice University

This graphene oxide “paper” was analyzed for its mechanical characteristics under strain by Rice University researchers. They discovered that the mechanical properties of the material change, depending on the rate of strain. Image credit: Ajayan Research Group/Rice University

The graphene oxide paper they tested was a stack of sheets that lay atop each other like pancakes. Oxygen molecules “functionalized” the surfaces, adding roughness to the otherwise atom-thick sheets.

In experiments and computer models, the team found that with gentle, slow stress, the oxides would indeed catch, causing the paper to take on a corrugated form where layers pulled apart. But a higher strain rate makes the material brittle. “The simulation performed by our collaborators in Brazil provides insight and confirms that if you pull it very fast, the layers don’t interact, and only one layer comes out,” Tiwary said.

“After this study, we now know there are some functional groups that are useful and some that are not. With this understanding we can choose the functional groups to make better structures at the molecular level.”

Source: Rice University

Featured news from related categories:

Technology Org App
Google Play icon
85,468 science & technology articles

Most Popular Articles

  1. New treatment may reverse celiac disease (October 22, 2019)
  2. The World's Energy Storage Powerhouse (November 1, 2019)
  3. "Helical Engine" Proposed by NASA Engineer could Reach 99% the Speed of Light. But could it, really? (October 17, 2019)
  4. Plastic waste may be headed for the microwave (October 18, 2019)
  5. Universe is a Sphere and Not Flat After All According to a New Research (November 7, 2019)

Follow us

Facebook   Twitter   Pinterest   Tumblr   RSS   Newsletter via Email