Disrupting the symmetrical structure of a solid-state topological crystalline insulator creates mass in previously mass-less electrons and imparts an unexpected level of control in this nascent class of materials, an international team of researchers reports in the current edition of Science Express.
The researchers not only confirmed several theoretical predictions about topological crystalline insulators (TCIs), but made a significant experimental leap forward that revealed even more details about the crystal structure and electronic behavior of these newly identified materials, according to Boston College Associate Professor of Physics Vidya Madhavan, one of the lead authors of the report.
The findings could pave the way for engineering the electronic properties of TCI surfaces towards novel functionalities at the nanoscale.
“There is a lot of rich physics here that’s waiting to be explored,” said Madhavan. “We’ve opened the door to better understanding topological crystalline insulators and the potential of these materials.”
Confirmed within the past few years, topological insulators possess interiors that behave like insulators, blocking the flow of electrons. Yet externally, they contain conducting states where electrons can move freely across their surfaces. A few years ago, physicists first posited the existence of TCIs, a new class of topological materials where conducting surface electrons are theorized to obey fundamental quantum laws set by the crystalline structure of the interior.
Starting with a TCI consisting of lead and selenium, researchers sought to disrupt its structural symmetry by provoking, or doping, the material through the addition of tin, Madhavan said. The subsequent disruption had a dramatic effect on mass-less “Dirac” electrons that are present within the material and behave as relativistic particles. The manipulation added mass to some of these electrons, which took their places side-by-side with the Dirac electrons, a startling result in a solid-state material, Madhavan said.